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Thermocatalytic conversion of wood-plastic composite over HZSM-5 catalysts.

Authors :: Seo J
Kim H
Jeon S
Valizadeh S
Khani Y
Jeon BH
Rhee GH
Chen WH
Lam S
Khan MA
Park YK
Source :: Bioresource technology [Bioresour Technol] 2023 Apr; Vol. 373, pp. 128702. Date of Electronic Publication: 2023 Feb 03.
Publication Year :: 2023
Abstract: Air gasification of the Wood-Plastic Composite (WPC) was performed over Ni-loaded HZSM-5 catalysts to generate H <subscript>2</subscript> -rich gas. Increasing SiO <subscript>2</subscript> /Al <subscript>2</subscript> O <subscript>3</subscript> ratio (SAR) of HZSM-5 adversely affected catalytic activity, where the highest gas yield (51.38 wt%) and H <subscript>2</subscript> selectivity (27.01 vol%) were acquired using 20 %Ni/HZSM-5(30) than those produced over 20 %Ni/HZSM-5(80) and 20 %Ni/HZSM-5(280). Reducing SAR was also favorably conducive to increasing the acyclic at the expense of cyclic compounds in oil products. These phenomena are attributed to enhanced acid strength and Ni dispersion of 20 %Ni/HZSM-5(30) catalyst. Moreover, catalytic activity in the terms of gas yield and H <subscript>2</subscript> selectivity enhanced with growing Ni loading to 20 %. Also, the addition of promoters (Cu and Ca) to 20 %Ni/HZSM-5(30) boosted the catalytic efficiency for H <subscript>2</subscript> -rich gas generation. Raising temperature indicated a positive relevance with the gas yield and H <subscript>2</subscript> selectivity. WPC valorization via gasification technology would be an outstanding outlook in the terms of a waste-to-energy platform.<br />Competing Interests: Declaration of Competing Interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.<br /> (Copyright © 2023 Elsevier Ltd. All rights reserved.)