Transition-Metal-Free Upscaling of 2,5-Furandicarboxylic Acid Synthesis and Investigation of the Reaction Mechanism.

Authors :: Lee TW
Lee WJ
Kim YS
Do T
Choi JE
Han YK
Oh C
Lee CW
Yum EK
Yang JW
Source :: Chemistry (Weinheim an der Bergstrasse, Germany) [Chemistry] 2023 Jun 27; Vol. 29 (36), pp. e202300903. Date of Electronic Publication: 2023 May 03.
Publication Year :: 2023
Abstract: An environmentally friendly oxidation system has proposed for the practical and scalable production of value-added 2,5-furandicarboxylic acid from 1 kg of 5-hydroxymethylfurfural. The system is composed of a simple base, oxygen, and a green solvent, thereby providing a sustainable and economical approach to organic synthesis. To gain insight into the mechanism of this oxidation process, NMR spectroscopic analysis and kinetic study are used for the mechanistic investigation of this environmentally friendly oxidation process.<br /> (© 2023 Wiley-VCH GmbH.)

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