Valorization of Boehmeria nivea stalk towards multipurpose fractionation: furfural, pulp, and phenolic monomers.

Background: As one of the most abundant bioresource in nature, the value-added utilization of lignocellulosic biomass is limited due to its inherent stubbornness. Pretreatment is a necessary step to break down the recalcitrance of cell walls and achieve an efficient separation of three main components (cellulose, hemicelluloses, and lignin).
Results: In this study, hemicelluloses and lignin in Boehmeria nivea stalks were selectively extracted with a recyclable acid hydrotrope, an aqueous solution of P-toluenesulfonic acid (p-TsOH). 79.86% of hemicelluloses and 90.24% of lignin were removed under a mild pretreatment condition, C80T80t20, (acid concentration of 80 wt%, pretreatment temperature and time of 80 °C and 20 min, respectively). After ultrasonic treatment for 10 s, the residual cellulose-rich solid was directly converted into pulp. Subsequently, the latter was utilized to produce paper via mixing with softwood pulp. The prepared handsheets with a pulp addition of 15 wt% displayed higher tear strength (8.31 mN m ² /g) and tensile strength (8.03 Nm/g) than that of pure softwood pulp. What's more, the hydrolysates of hemicelluloses and the extracted lignin were transformed to furfural and phenolic monomers with yields of 54.67% and 65.3%, respectively.
Conclusions: The lignocellulosic biomass, Boehmeria nivea stalks, were valorized to pulp, furfural, and phenolic monomers, successfully. And a potential solution of comprehensive utilization of Boehmeria nivea stalks was provided in this paper.
(© 2023. The Author(s).)