Microstructure Characteristics and Hydrogen Storage Kinetics of Mg 77+ x Ni 20- x La 3 ( x = 0, 5, 10, 15) Alloys.

Mg _{77+ x} Ni _{20- x} La ₃ ( x = 0, 5, 10, 15) alloys were successfully prepared by the vacuum induction melting method. The structural characterizations of the alloys were performed by using X-ray diffraction and scanning electron microscope. The effects of nickel content on the microstructure and hydrogen storage kinetic of the as-cast alloys were investigated. The results showed that the alloys are composed of a primary phase of Mg ₂ Ni, lamella eutectic composites of Mg + Mg ₂ Ni, and some amount of LaMg ₁₂ and La ₂ Mg ₁₇ . Nickel addition significantly improved the hydrogen-absorption kinetic performance of the alloy. At 683 K, Mg ₇₇ Ni ₂₀ La ₃ alloy and Mg ₈₂ Ni ₁₅ La ₃ alloy underwent hydrogen absorption and desorption reactions for 2 h, respectively, and their hydrogen absorption and desorption capacities were 4.16 wt.% and 4.1 wt.%, and 4.92 wt.% and 4.69 wt.%, respectively. Using the Kissinger equation, it was calculated that the activation energy values of Mg ₇₇ Ni ₂₀ La ₃ , Mg ₈₂ Ni ₁₅ La ₃ , Mg ₈₇ Ni ₁₀ La ₃ and Mg ₉₂ Ni ₅ La ₃ alloys were in the range of 68.5~75.2 kJ/mol, much lower than 150~160 kJ/mol of MgH ₂ .