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ArI(NTf 2 ) 2 : the boundary of oxidative capacity for ArIL 2 ?
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2023 Nov 07; Vol. 59 (89), pp. 13340-13343. Date of Electronic Publication: 2023 Nov 07. - Publication Year :
- 2023
-
Abstract
- Synthesis and crystallographic characterization of NO <subscript>2</subscript> -C <subscript>6</subscript> H <subscript>4</subscript> -I(NTf <subscript>2</subscript> ) <subscript>2</subscript> (NTf <subscript>2</subscript> = bistriflimide) is reported. Experimental results find that this compound can perform oxidation reactions that ArI(OTf) <subscript>2</subscript> is unable to and theoretical analysis indicates Ar-I(NTf <subscript>2</subscript> ) <subscript>2</subscript> is the most oxidizing in the ArIL <subscript>2</subscript> class of compounds known and may also be the most oxidizing compound in the class practically possible.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 59
- Issue :
- 89
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 37869995
- Full Text :
- https://doi.org/10.1039/d3cc04563c