Crystal structure and Hirshfeld surface analysis of poly[[tetra-aqua-(μ-1,3,4,7,8,10,12,13,16,17,19,22-dodeca-aza-tetra-cyclo-[8.8.4.1 3,17 .1 8,12 ]tetra-cosane-5,6,14,15,20,21-hexaonato)iron(IV)dilithium] tetra-hydrate].

Authors :: Plutenko MO
Shova S
Pavlenko VA
Golenya IA
Fritsky IO
Source :: Acta crystallographica. Section E, Crystallographic communications [Acta Crystallogr E Crystallogr Commun] 2023 Oct 19; Vol. 79 (Pt 11), pp. 1059-1062. Date of Electronic Publication: 2023 Oct 19 (Print Publication: 2023).
Publication Year :: 2023
Abstract: The title compound, [FeLi <subscript>2</subscript> (C <subscript>12</subscript> H <subscript>12</subscript> N <subscript>12</subscript> O <subscript>6</subscript> )(H <subscript>2</subscript> O) <subscript>4</subscript> ]·4H <subscript>2</subscript> O, consists of iron complex anions, lithium cations and water mol-ecules. The complex anion shows a clathrochelate topology. The coordination geometry of the Fe <superscript>IV</superscript> centre is inter-mediate between a trigonal prism and a trigonal anti-prism. In the crystal, the complex anions are connected through two Li cations into dimers, which are connected by Li-O bonds, forming infinite chains along the b- axis direction.<br /> (© Plutenko et al. 2023.)

Language :: English
ISSN :: 2056-9890
Volume :: 79
Issue :: Pt 11
Database :: MEDLINE
Journal :: Acta crystallographica. Section E, Crystallographic communications
Publication Type :: Academic Journal
Accession number :: 37936846
Full Text :: https://doi.org/10.1107/S2056989023008587

Full Text Access

Tools