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Cyclopentadienyl capped thorium(IV) porphyrinoid complex.

Authors :
Mangel DN
Brewster JT
Juarez GJ
Lynch VM
Sessler JL
Source :
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Jan 23; Vol. 60 (8), pp. 1020-1022. Date of Electronic Publication: 2024 Jan 23.
Publication Year :
2024

Abstract

The reaction between Th(IV) dipyriamethyrin dichloride and sodium cyclopentadienyl (Cp) results in the formation of a cyclopentadienyl capped thorium dipyriamethyrin complex, which to our knowledge represents the first expanded porphyrin f-element Cp complex.

Details

Language :
English
ISSN :
1364-548X
Volume :
60
Issue :
8
Database :
MEDLINE
Journal :
Chemical communications (Cambridge, England)
Publication Type :
Academic Journal
Accession number :
38170623
Full Text :
https://doi.org/10.1039/d3cc05283d