Vertical distributions and potential contamination assessment of seldom monitored trace elements in three different land use types of Yellow River Delta.

The Yellow River Delta (YRD) is the second largest petrochemical base in China and the impact of human activities has been continuously increasing in recent decades, however, the contamination status of seldom monitored trace elements (SMTEs) in YRD has rarely been reported. This study evaluated the levels, vertical distributions, contamination status and sources of SMTEs in soil samples of three different land use types in YRD. The results indicated that the vertical distributions of SMTEs contents showed a gradually upward increasing trend for the soil profiles of black locust forest, while the SMTEs contents displayed a gradually upward decreasing trend for the soil profiles of cotton field. However, the SMTEs contents in the oil field area showed no significant difference among different depths. The vertical distributions of SMTEs were very likely related to the anthropogenic disturbance in the later stage. The environmental pollution status assessment of SMTEs showed obvious enrichment of Cs, Sn, and U in the soils of YRD. Moreover, the potential source analysis based on multivariate statistical methods indicated that Ga, Rb, Cs, Sc, Sn, Tl, Be, Bi, Ca and Mo were clustered together and positively correlated with Al, Fe, Mg and K, and may be mainly associated with geochemical weathering process, while the Ce, La, Th, U, Nb, Ta, and Hf may be impacted by both natural process and human activities. Though the SMTEs pollution status was not very serious, our results highlighted the non-negligible influence of anthropogenic activities on vertical distributions of SMTEs in three different land use types from YRD. Our results provide valuable information for understanding the vertical distribution and pollution status of SMTEs in YRD.
Competing Interests: Declaration of competing interest The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.
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