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Palladium-Catalyzed C2-Selective Direct Arylation of Benzo[ b ]thiophene 1,1-Dioxides with Arylboronic Acids.
- Source :
-
ACS omega [ACS Omega] 2023 Dec 19; Vol. 9 (1), pp. 1738-1747. Date of Electronic Publication: 2023 Dec 19 (Print Publication: 2024). - Publication Year :
- 2023
-
Abstract
- A novel oxidative cross-coupling of benzo[ b ]thiophene 1,1-dioxides with arylboronic acids was reported. The efficient reaction occurred at the C2-position via C-H activation, followed by Pd(II)-catalyzed arylation. Furthermore, a series of C2-arylated products with significant photoluminescence properties have been synthesized and characterized, which illustrates the potential applications of our method in the aggregation-induced emission field.<br />Competing Interests: The authors declare no competing financial interest.<br /> (© 2023 The Authors. Published by American Chemical Society.)
Details
- Language :
- English
- ISSN :
- 2470-1343
- Volume :
- 9
- Issue :
- 1
- Database :
- MEDLINE
- Journal :
- ACS omega
- Publication Type :
- Academic Journal
- Accession number :
- 38222557
- Full Text :
- https://doi.org/10.1021/acsomega.3c08334