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Chiral Transfer of Linear Polysiloxane with Preferred-Handed Helical Conformation.
- Source :
-
ACS macro letters [ACS Macro Lett] 2024 May 21; Vol. 13 (5), pp. 537-541. Date of Electronic Publication: 2024 Apr 17. - Publication Year :
- 2024
-
Abstract
- We report the preparation of chiral silica using a linear polysiloxane main chain with a preferred-handed helical structure as the template. Poly(methylvinyl siloxane) (PMVS) with a cysteine derivative side chain designated as PMVS-Cys was prepared using anionic polymerization and an ene-thiol reaction. PMVS-Cys forms a helical conformation in both solution and film via hydrogen bonding between amide groups at side chains. The helical structure remains during the calcination process, resulting in silica with helical structure. The silica with a helical structure shows optical activity.
Details
- Language :
- English
- ISSN :
- 2161-1653
- Volume :
- 13
- Issue :
- 5
- Database :
- MEDLINE
- Journal :
- ACS macro letters
- Publication Type :
- Academic Journal
- Accession number :
- 38629809
- Full Text :
- https://doi.org/10.1021/acsmacrolett.4c00122