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Iron-catalyzed decarboxylative radical addition to chiral azomethine imines upon visible light.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Jun 13; Vol. 60 (49), pp. 6316-6319. Date of Electronic Publication: 2024 Jun 13. - Publication Year :
- 2024
-
Abstract
- Herein, we disclose an eco-efficient redox-neutral iron-catalyzed decarboxylative radical addition to chiral azomethine imines upon visible light (427 nm) giving cyclic hydrazine derivatives with dr ranging from 82 : 18 to >96 : 4. This earth-abundant metal promoted sequence proceeds efficiently under ligand-free conditions based on a LMCT process and opens a route to new chiral heterocycles.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 60
- Issue :
- 49
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 38819219
- Full Text :
- https://doi.org/10.1039/d4cc01766h