Back to Search
Start Over
Electrochemical hydrocarboxylation of enol derivatives with CO 2 : access to β-acetoxycarboxylic acids.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2024 Jul 30; Vol. 60 (62), pp. 8099-8102. Date of Electronic Publication: 2024 Jul 30. - Publication Year :
- 2024
-
Abstract
- Electrochemical hydrocarboxylation of enol acetates with CO <subscript>2</subscript> is developed. The disclosed process provides β-acetoxycarboxylic acids in 25-66% yields, in contrast to the electrolysis of ketones, silyl enol ethers and vinyl tosylates with CO <subscript>2</subscript> , which leads mainly to alcohols.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Volume :
- 60
- Issue :
- 62
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 38993133
- Full Text :
- https://doi.org/10.1039/d4cc02831g