Concurrent Pressure-Induced Superconductivity and Photoconductivity Transitions in PbSe 0.5 Te 0.5 .

Concurrent superconductivity and negative photoconductivity (NPC) are rarely observed. Here, the discovery in PbSe _0.5 Te _0.5 of superconductivity and photoconductivity transitions between positive photoconductivity (PPC) and NPC during compression is reported to ≈40 GPa and subsequent decompression, which are also accompanied by reversible structure transitions (3D Fm 3 ¯ ${{\bar{3}}}$ m ⇌ 2D Pnma ⇌ 3D Pm 3 ¯ ${{\bar{3}}}$ m). Superconductivity with a maximum T _c of ≈6.7 K coincides with NPC and structure transition of Pnma to Pm 3 ¯ ${{\bar{3}}}$ m at ≈18 GPa and the latter phase is preserved down to ≈5 GPa with enhanced T _c of ≈6.9 K during decompression. The observations imply the simultaneous superconducting and photoconductive transitions are closely related to the metallic Pm 3 ¯ ${{\bar{3}}}$ m phase. First-principles calculations suggest the enhanced p-p hybridization and charge transfer between Pb-5p and ligand-p orbitals near the Fermi surface play key roles in electron-phonon interaction of mediating the Cooper pairs in PbSe _0.5 Te _0.5 . Hall coefficient measurements reveal that photothermal effect enhances electron-phonon interplay, which decreases carrier concentration and mobility and results in the reversal of PPC-NPC. Structure-dependent superconductivity and NPC are jointly mediated by electron-phonon interplay, which is tunable through illumination or cooling at high-pressure. The findings shed light on the origin of superconductive and photoconductive transitions in versatile materials of lead chalcogenides.
(© 2024 Wiley‐VCH GmbH.)