Photocatalytic degradation of polycyclic aromatic hydrocarbons under visible light irradiation in water using TiO 2 /MgO nanocomposites.

An extensive class of pollutants found in soil, water, and bottom sediments are categorized as polycyclic aromatic hydrocarbons. A possible method of breaking down polycyclic aromatic hydrocarbons is thought to be the photochemical approach. The potential application of mesoporous nanocomposites on TiO ₂ /MgO as catalysts for the photooxidation of polycyclic aromatic hydrocarbons under the influence of visible light was assessed in this work. TiO ₂ /MgO nanocomposites were successfully obtained by the self-propagating high-temperature synthesis using methotitanic acid and magnesium nitrate as metal precursors. An important step in the synthesis was the conversion of the titanium precursor into a water-soluble form with the subsequent addition of glycine and citric acid at a carbon/nitrogen (C/N) molar ratio of 0.25. This synthesis via solutions allowed the target materials with major phases of magnesium metatitanate MgTiO ₃ , magnesium dititanate MgTi ₂ O ₅ , and magnesium titanate Mg ₂ TiO ₄ to be obtained after heat treatment at 750 °C. Heterostructured mesoporous TiO ₂ /MgO powders with a specific surface area of 22.0-28.4 m ² /g had an average diameter of the predominant pores of 10-30 nm. The greatest degree of photocatalytic oxidation of fluorene, pyrene, and benzpyrene (80, 68, and 53%, respectively) was obtained when it was combined with the TiO ₂ /MgTi ₂ O ₅ /MgTiO ₃ nanocomposite under visible light irradiation. This study showed that mesoporous TiO ₂ /MgO nanocomposites could be used as photooxidation catalysts for polycyclic aromatic hydrocarbons. The maximum level of photocatalytic oxidation of polycyclic aromatic hydrocarbons in TiO ₂ /MgO nanocomposites occurred at pH 7 and a photocatalyst dose of 1 mg/L under the influence of normal solar radiation.
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(© 2025. The Author(s).)