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A [CuII24] truncated octahedron and its [CuII8] building block.
- Source :
-
Chemical communications (Cambridge, England) [Chem Commun (Camb)] 2025 Mar 03. Date of Electronic Publication: 2025 Mar 03. - Publication Year :
- 2025
- Publisher :
- Ahead of Print
-
Abstract
- Reaction of CuCl <subscript>2</subscript> ·2H <subscript>2</subscript> O with p-tert -butylthiacalix[4]arene (H <subscript>4</subscript> TC[4]A) affords a [CuII24] cage whose metallic skeleton conforms to a truncated octahedron in which the metal ions are strongly antiferromagnetically coupled. A structurally related [CuII8] cluster can be made using CuBr <subscript>2</subscript> in an otherwise identical reaction.
Details
- Language :
- English
- ISSN :
- 1364-548X
- Database :
- MEDLINE
- Journal :
- Chemical communications (Cambridge, England)
- Publication Type :
- Academic Journal
- Accession number :
- 40026000
- Full Text :
- https://doi.org/10.1039/d5cc00532a