Seasonal variations in groundwater chemistry and quality and associated health risks from domestic wells and crucial constraints in the Pearl River Delta.

Groundwater quality is strongly compromised by polluted surface water recharge in rapidly developing urban regions. However, gaps still remain in the understanding of the critical contaminants controlling water quality and the health risks associated with groundwater consumption, particularly considering seasonal and climate changes in rainfall. This work focused on changes in groundwater quality and critical contaminants in domestic wells in the fast-developing Pearl River Delta (PRD) from the wet season to the dry season. The stable isotope δ D and δ ¹⁸ O values indicated that groundwater was largely impacted by precipitation and has experienced strong evaporation. The groundwater generally exhibited oxidizing and slightly alkaline properties and was predominantly of the Ca-HCO ₃ type. Owing to the dominant water type of Ca-HCO ₃ and the high concentrations of Ca, concerns related to hard water arose, particularly during the wet season, which promotes the need for water softening before groundwater use. Although the heavy metal pollution index (HPI) and water quality index (WQI) indicated excellent or good water quality, 34% and 47% of the groundwater samples presented elevated concentrations of arsenic and nitrate, respectively, compared with the WHO recommended levels, and the contamination level was elevated during the dry season. To our knowledge, this study is the first to report the fluoride concentrations in the PRD groundwater, with median values below 0.5 mg L ^-1 , underscoring the need for dietary fluoride supplementation. Health risk assessment confirmed the presence of both noncarcinogenic risks from arsenic and nitrate and cancer risk from arsenic in local populations resulting from groundwater consumption in the PRD region. This research emphasizes the importance of critical contaminants that constrain groundwater quality from different seasons with large variations in rainfall. Our work highlights the urgent need for the construction of adequate sanitation systems and for the control of agricultural nonpoint source pollution in rapidly urbanizing areas to safeguard both surface water and groundwater resources.