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Synthesis and molecular structure of an abnormal carbene-gallium chloride complex.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 2014, Vol. 43 Issue 38, p14211-14214, 4p
- Publication Year :
- 2014
-
Abstract
- Low temperature reaction of N-heterocyclic carbene : BEt<subscript>3</subscript> with nBuLi (in THF) initially gives the C4-lithiated N-heterocyclic carbene : BEt<subscript>3</subscript> complex (4), which isomerizes to the C2-lithiated abnormal N-heterocyclic carbene : BEt<subscript>3</subscript> complex (2) in refluxing THF. While reaction of 2 with GaCl<subscript>3</subscript> gives a 4-functionalized N-heterocyclic carbene : GaCl<subscript>3</subscript> adduct (6), reaction of 4 with GaCl<subscript>3</subscript> affords the first abnormal carbene-gallium chloride complexes (5). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 43
- Issue :
- 38
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 100103291
- Full Text :
- https://doi.org/10.1039/c4dt00933a