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Adaptive behavior of a redox-active gallium carbenoid in complexes with molybdenum.
- Source :
- Chemical Communications; 2014, Vol. 50 Issue 70, p10108-10111, 4p
- Publication Year :
- 2014
-
Abstract
- A gallium(I) carbenoid derived from redox-active diimine 1,2-bis[(2,6-diisopropylphenyl)imino]acenaphthene (dpp-bian) in complexes with molybdenum may serve either as a neutral [(dpp-bian)Ga:] or an anionic [(dpp-bian)Ga:]<superscript>-</superscript> two-electron donor depending on the electronic state of the transition metal. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 50
- Issue :
- 70
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 100147044
- Full Text :
- https://doi.org/10.1039/c4cc04019h