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Oxidative transformations of amidophenolate complexes of gallium( iii).
- Source :
- Russian Chemical Bulletin; Apr2014, Vol. 63 Issue 4, p916-922, 7p
- Publication Year :
- 2014
-
Abstract
- The oxidation of the earlier synthesized [4,6-di- tert-butyl- N-(2,6-diisopropylphenyl)- o-amidophenolato]methylgallium( iii) ( 1a) and [4,6-di- tert-butyl- N-(2,6-diisopropylphenyl)- o-amidophenolato]iodogallium( iii) ( 1b) by different reagents, such as mercury( ii) salts, molecular iodine, and tetramethylthiuram disulfide, was studied. The oxidation of the starting diamagnetic compounds gives pentacoordinated gallium( iii) bis- o-iminosemiquinolates 4-7 as the major products, which are generated as a result of the further disproportionation of intermediate monoradical tetracoordinated metal complexes. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 10665285
- Volume :
- 63
- Issue :
- 4
- Database :
- Complementary Index
- Journal :
- Russian Chemical Bulletin
- Publication Type :
- Academic Journal
- Accession number :
- 100640655
- Full Text :
- https://doi.org/10.1007/s11172-014-0528-4