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From selenidostannates to silver-selenidostannate: structural variation of chalcogenidometallates synthesized in ionic liquids.
- Source :
- Chemical Communications; 2013, Vol. 49 Issue 2, p181-183, 3p
- Publication Year :
- 2013
-
Abstract
- Presented here are the ionothermal preparation and structural variation of selenidostannates, whose structures can be tuned by varying the combination of ionic liquids and auxiliary amines as mixed solvent, as well as changing the reaction temperature and time. Remarkably, a silver-selenidostannate compound featuring lamellar structure was achieved by unusual insertion of linear two-coordinate Ag<superscript>+</superscript> ions between the {Sn<subscript>3</subscript>Se<subscript>7</subscript>}<subscript>n</subscript><superscript>2n−</superscript> double chains. [ABSTRACT FROM AUTHOR]
- Subjects :
- IONIC liquids
AMINES
SILVER ions
CHALCOGENIDES
FUSED salts
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 49
- Issue :
- 2
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 100863762
- Full Text :
- https://doi.org/10.1039/c2cc37051d