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Palladacycle-catalyzed phosphonation of aryl halides in neat water.
- Source :
- Green Chemistry; 2013, Vol. 15 Issue 4, p1055-1060, 6p
- Publication Year :
- 2013
-
Abstract
- An efficient and generally applicable protocol for the palladacycle-catalyzed arylation of diisopropyl H-phosphonate in water was developed. The remarkable features of this C–P bond-forming reaction include wide substrate scope including the inactive electron-rich and electron-neutral aryl chlorides, the weak inorganic base KF instead of strong bases such as KO<superscript>t</superscript>Bu or NaO<superscript>t</superscript>Bu for the activation of C–Cl bond, and the addition of isopropanol to avoid the decomposition of diisopropyl H-phosphonate. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14639262
- Volume :
- 15
- Issue :
- 4
- Database :
- Complementary Index
- Journal :
- Green Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 100867809
- Full Text :
- https://doi.org/10.1039/c3gc00030c