Using XCO2 retrievals for assessing the long-term consistency of NDACC/FTIR data sets.

Within the NDACC (Network for the Detection of Atmospheric Composition Change), more than 20 FTIR (Fourier-transform infrared) spectrometers, spread worldwide, provide long-term data records of many atmospheric trace gases. We present a method that uses measured and modelled XCO₂ for assessing the consistency of these NDACC data records. Our XCO₂ retrieval setup is kept simple so that it can easily be adopted for any NDACC/FTIR-like measurement made since the late 1950s. By a comparison to coincident TCCON (Total Carbon Column Observing Network) measurements, we empirically demonstrate the useful quality of this suggested NDACC XCO₂ product (empirically obtained scatter between TCCON and NDACC is about 4‰ for daily mean as well as monthly mean comparisons, and the bias is 25 ‰). Our XCO₂ model is a simple regression model fitted to CarbonTracker results and the Mauna Loa CO₂ in situ records. A comparison to TCCON data suggests an uncertainty of the model for monthly mean data of below 3 ‰.We apply the method to the NDACC/FTIR spectra that are used within the project MUSICA (multi-platform remote sensing of isotopologues for investigating the cycle of atmospheric water) and demonstrate that there is a good consistency for these globally representative set of spectra measured since 1996: the scatter between the modelled and measured XCO₂ on a yearly time scale is only 3 ‰. [ABSTRACT FROM AUTHOR]