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An organic-ligand-free thermochromic luminescent cuprous iodide trinuclear cluster: evidence for cluster centered emission and configuration distortion with temperature.
- Source :
- Chemical Communications; 5/11/2015, Vol. 51 Issue 38, p8062-8065, 4p
- Publication Year :
- 2015
-
Abstract
- An organic-ligand-free cuprous iodide trinuclear cluster with significant temperature-dependent structural distortion has been synthesized and characterized, which shows thermochromic luminescence originating from a single cluster-centered triplet due to the absence of an organic ligand. This compound also shows interesting reversible temperature dependent phase transition from chiral to centrosymmetric space groups. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 51
- Issue :
- 38
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 102328944
- Full Text :
- https://doi.org/10.1039/c5cc01154j