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Flexible cathodes and multifunctional interlayers based on carbonized bacterial cellulose for high-performance lithium–sulfur batteries.
- Source :
- Journal of Materials Chemistry A; 5/28/2015, Vol. 3 Issue 20, p10910-10918, 9p
- Publication Year :
- 2015
-
Abstract
- A three-dimensional (3D) carbonaceous aerogel derived from sustainable bacterial cellulose (BC) is introduced as a flexible framework for sulfur in lithium–sulfur batteries. The 3D carbonized BC (CBC) with highly interconnected nanofibrous structure exhibits good electrical conductivity and mechanical stability. The intrinsic macroporous structure of CBC contributes to a high sulfur loading of 81 wt%. Microstructure and morphology characterization results demonstrate that the sulfur species wrapped around CBC nanofibers are well dispersed. Even at such a high loading, the S/CBC composite still contains sufficient free space to accommodate the volume expansion of sulfur during lithiation. Furthermore, with an ultralight CBC interlayer inserted between the sulfur cathode and separator, significant improvement is achieved in active material utilization, cycling stability, and coulombic efficiency. The CBC interlayer can provide an extra conductive framework and adsorb migrating polysulfides to a certain degree. The CBC interlayer can also act as an additional collector for sulfur and thus could prevent the over-aggregation of insulated sulfur on the cathode surface. The good electrochemical performance reported in this work can be ascribed to the flexible 3D-interconnected nanostructure of the carbon framework and the rational design of battery configuration. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 20507488
- Volume :
- 3
- Issue :
- 20
- Database :
- Complementary Index
- Journal :
- Journal of Materials Chemistry A
- Publication Type :
- Academic Journal
- Accession number :
- 102625794
- Full Text :
- https://doi.org/10.1039/c5ta01515d