Giant negative thermal expansion covering room temperature in nanocrystalline GaNxMn3.

Nanocrystalline antiperovskite GaN_xMn₃ powders were prepared by mechanically milling. The micrograin GaN_xMn₃ exhibits an abrupt volume contraction at the antiferromagnetic (AFM) to paramagnetic (PM) (AFM-PM) transition. The temperature window of volume contraction (ΔT) is broadened to 50 K as the average grain size (〈D〉) is reduced to ~30 nm. The corresponding coefficient of linear thermal expansion (α) reaches ~ -70 ppm/K, which are comparable to those of giant NTE materials. Further reducing 〈D〉 to ~10 nm, ΔT exceeds 100 K and α remains as large as -30 ppm/K (-21 ppm/K) for x = 1.0 (x = 0.9). Excess atomic displacements together with the reduced structural coherence, revealed by high-energy X-ray pair distribution functions, are suggested to delay the AFM-PM transition. By controlling 〈D〉, giant NTE may also be achievable in other materials with large lattice contraction due to electronic or magnetic phase transitions. [ABSTRACT FROM AUTHOR]