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CaII-Catalyzed Alkenylation of Alcohols with Vinylboronic Acids.

Authors :
Leboeuf, David
Presset, Marc
Michelet, Bastien
Bour, Christophe
Bezzenine-Lafollée, Sophie
Gandon, Vincent
Source :
Chemistry - A European Journal; 7/27/2015, Vol. 21 Issue 31, p11001-11005, 5p
Publication Year :
2015

Abstract

Direct alkenylation of a variety of alcohols with vinylboronic acids has been accomplished using the airstable calcium(II) complex Ca(NTf<subscript>2</subscript>)<subscript>2</subscript> under mild conditions with short reaction times. For reluctant transformations, an ammonium salt was used as an additive to circumvent the reactivity issue. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
09476539
Volume :
21
Issue :
31
Database :
Complementary Index
Journal :
Chemistry - A European Journal
Publication Type :
Academic Journal
Accession number :
110145086
Full Text :
https://doi.org/10.1002/chem.201501677