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Nitrite-Templated Synthesis of Lanthanide-Containing [2]Rotaxanes for Anion Sensing.
- Source :
- Angewandte Chemie International Edition; 10/20/2014, Vol. 53 Issue 43, p11463-11466, 4p
- Publication Year :
- 2014
-
Abstract
- The first anion-templated synthesis of a lanthanidecontaining interlocked molecule is demonstrated by utilizing a nitrite anion to template initial pseudorotaxane formation. Subsequent stoppering of the interpenetrated assembly allows for the preparation of a lanthanide-functionalized [2]rotaxane in high yield. Following removal of the nitrite anion template, the europium [2]rotaxane host is demonstrated to recognize and sense fluoride selectively. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 53
- Issue :
- 43
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 110198440
- Full Text :
- https://doi.org/10.1002/anie.201405131