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Direct gem-difluoromethylenation of sp3-hybridized carbon center through copper-mediated radical/radical cross-coupling for the construction of a CH2–CF2 linkage.
- Source :
- Chemical Communications; 11/11/2015, Vol. 51 Issue 87, p15756-15759, 4p
- Publication Year :
- 2015
-
Abstract
- Efficient direct gem-difluoromethylenation of an sp<superscript>3</superscript>-hybridized carbon center in benzyl bromides using benzo-1,3-azolic (oxa-, thia- or aza-) difluoromethyl bromides for construction of a CH<subscript>2</subscript>–CF<subscript>2</subscript> linkage has been developed through radical/radical C–C cross-coupling via two separate single electron transfer processes (SET) under the promotion of different copper sources. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 51
- Issue :
- 87
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 110534932
- Full Text :
- https://doi.org/10.1039/c5cc05677b