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Single-Crystal Y2O3 Epitaxially on GaAs(001) and (111) Using Atomic Layer Deposition.
- Source :
- Materials (1996-1944); 2015, Vol. 8 Issue 10, p7084-7093, 10p, 2 Color Photographs, 3 Graphs
- Publication Year :
- 2015
-
Abstract
- Single-crystal atomic-layer-deposited (ALD) Y<subscript>2</subscript>O<subscript>3</subscript> films 2 nm thick were epitaxially grown on molecular beam epitaxy (MBE) GaAs(001)-4 × 6 and GaAs(111)A-2 × 2 reconstructed surfaces. The in-plane epitaxy between the ALD-oxide films and GaAs was observed using \textit{in-situ} reflection high-energy electron diffraction in our uniquely designed MBE/ALD multi-chamber system. More detailed studies on the crystallography of the hetero-structures were carried out using high-resolution synchrotron radiation X-ray diffraction. When deposited on GaAs(001), the Y<subscript>2</subscript>O<subscript>3</subscript> films are of a cubic phase and have (110) as the film normal, with the orientation relationship being determined: Y<subscript>2</subscript>O<subscript>3</subscript>(110)[001][110]//GaAs(001)[110][110]. On GaAs(111)A, the Y<subscript>2</subscript>O<subscript>3</subscript> films are also of a cubic phase with (111) as the film normal, having the orientation relationship of Y<subscript>2</subscript>O<subscript>3</subscript>(111)[211] [011]//GaAs (111) [211][011]. The relevant orientation for the present/future integrated circuit platform is (001). The ALD-Y<subscript>2</subscript>O<subscript>3</subscript>/GaAs(001)-4 × 6 has shown excellent electrical properties. These include small frequency dispersion in the capacitance-voltage CV curves at accumulation of ~7% and ~14% for the respective p- and n-type samples with the measured frequencies of 1 MHz to 100 Hz. The interfacial trap density (Dit) is low of ~1012 cm-2eV-1 as extracted from measured quasi-static CVs. The frequency dispersion at accumulation and the Dit are the lowest ever achieved among all the ALD-oxides on GaAs(001). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 19961944
- Volume :
- 8
- Issue :
- 10
- Database :
- Complementary Index
- Journal :
- Materials (1996-1944)
- Publication Type :
- Academic Journal
- Accession number :
- 110639109
- Full Text :
- https://doi.org/10.3390/ma8105364