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Accordion-like swelling of layered perovskite crystals via massive permeation of aqueous solutions into 2D oxide galleries.

Authors :
Song, Yeji
Iyi, Nobuo
Hoshide, Tatsumasa
Ozawa, Tadashi C.
Ebina, Yasuo
Ma, Renzhi
Miyamoto, Nobuyoshi
Sasaki, Takayoshi
Source :
Chemical Communications; 12/14/2015, Vol. 51 Issue 96, p17068-17071, 4p
Publication Year :
2015

Abstract

Platelet crystals of a layered perovskite showed massive accordion-like swelling in a tetrabutylammonium hydroxide solution. The permeation of the solution induced the huge expansion of the interlayer spacing as well as the crystal thickness up to 50-fold, leading to a very high water content of >90 wt%. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
51
Issue :
96
Database :
Complementary Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
111079221
Full Text :
https://doi.org/10.1039/c5cc05408g