Back to Search Start Over

A [3Fe–3S]3+ cluster with exclusively μ-sulfide donors.

Authors :
Lee, Yousoon
Jeon, Ie-Rang
Abboud, Khalil A.
García-Serres, Ricardo
Shearer, Jason
Murray, Leslie J.
Source :
Chemical Communications; 1/21/2016, Vol. 52 Issue 6, p1174-1177, 4p
Publication Year :
2016

Abstract

A [3Fe–3(μ-S)]<superscript>3+</superscript> cluster is reported in which each ferric center has a distorted trigonal pyramidal geometry, with an S = 1/2 ground state for the cluster and unusually anisotropic hyperfine coupling constants as determined by variable temperature magnetometry and Mössbauer spectroscopy. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
13597345
Volume :
52
Issue :
6
Database :
Complementary Index
Journal :
Chemical Communications
Publication Type :
Academic Journal
Accession number :
112085891
Full Text :
https://doi.org/10.1039/c5cc07813j