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A [3Fe–3S]3+ cluster with exclusively μ-sulfide donors.
- Source :
- Chemical Communications; 1/21/2016, Vol. 52 Issue 6, p1174-1177, 4p
- Publication Year :
- 2016
-
Abstract
- A [3Fe–3(μ-S)]<superscript>3+</superscript> cluster is reported in which each ferric center has a distorted trigonal pyramidal geometry, with an S = 1/2 ground state for the cluster and unusually anisotropic hyperfine coupling constants as determined by variable temperature magnetometry and Mössbauer spectroscopy. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 6
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 112085891
- Full Text :
- https://doi.org/10.1039/c5cc07813j