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Iron- and Cobalt-Catalyzed Synthesis of Carbene Phosphinidenes.
- Source :
- Angewandte Chemie International Edition; 1/26/2016, Vol. 55 Issue 5, p1690-1693, 4p
- Publication Year :
- 2016
-
Abstract
- In the presence of stoichiometric or catalytic amounts of [M{N(SiMe<subscript>3</subscript>)<subscript>2</subscript>}<subscript>2</subscript>] (M=Fe, Co), N-heterocyclic carbenes (NHCs) react with primary phosphines to give a series of carbene phosphinidenes of the type (NHC)⋅PAr. The formation of (IMe<subscript>4</subscript>)⋅PMes (Mes=mesityl) is also catalyzed by the phosphinidene-bridged complex [(IMe<subscript>4</subscript>)<subscript>2</subscript>Fe(μ-PMes)]<subscript>2</subscript>, which provides evidence for metal-catalyzed phosphinidene transfer. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 55
- Issue :
- 5
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 112377324
- Full Text :
- https://doi.org/10.1002/anie.201508303