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Water-Stable Homochiral Cluster Organic Frameworks Built by Two Kinds of Large Tetrahedral Cluster Units.
- Source :
- Chemistry - A European Journal; Feb2016, Vol. 22 Issue 8, p2611-2615, 5p
- Publication Year :
- 2016
-
Abstract
- Compared with metal organic frameworks (MOFs), the proton conductivity of cluster organic frameworks has been less studied. Herein, two supertetrahedral cluster organic frameworks (SCOFs) have been made that show two-fold interpenetrated networks built by trivalent lanthanide tetrahedral clusters and monovalent cuprous T<subscript>3</subscript>-supertetrahedral clusters. The structure analysis, second harmonic generation signals, and solid-state circular dichroism spectroscopy consistently reveal the chirality of these SCOFs. Remarkably, the water-stable SCOFs show a high proton conductivity value of 1.4×10<superscript>−3</superscript> S cm<superscript>−1</superscript> at 80 °C and 95 % RH (relative humidity). [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09476539
- Volume :
- 22
- Issue :
- 8
- Database :
- Complementary Index
- Journal :
- Chemistry - A European Journal
- Publication Type :
- Academic Journal
- Accession number :
- 112926048
- Full Text :
- https://doi.org/10.1002/chem.201505125