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Study of Stereocontrolling Elements in Chiral Phosphoric Acid Catalyzed Addition Reaction of Vinylindoles with Azlactones.
- Source :
- Synlett; 2016, Vol. 27 Issue 4, p581-585, 5p
- Publication Year :
- 2016
-
Abstract
- DFT studies were carried out to clarify the reaction mechanism and the stereocontrolling elements in the addition reaction of vinylindoles with azlactones catalyzed by a chiral phosphoric acid. The results suggest that the reaction proceeds via a six-membered transition state that is composed of the vinyl group of vinylindole and the enol moiety of azlactone. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 09365214
- Volume :
- 27
- Issue :
- 4
- Database :
- Complementary Index
- Journal :
- Synlett
- Publication Type :
- Academic Journal
- Accession number :
- 113146495
- Full Text :
- https://doi.org/10.1055/s-0035-1561677