Polypropylene-based composites containing sorbitol-based nucleating agent and siloxane-silsesquioxane resin.

ABSTRACT Composites based on isotactic polypropylene (iPP) modified with a sorbitol derivative (NX8000) and siloxane-silsesquioxane resin containing reactive phenyl groups (SiOPh) were prepared by melt extrusion. These iPP-based formulations were investigated to evaluate the influence of such additives on the crystallization behavior and morphology, as well as on thermal and mechanical properties. The addition of sorbitol fastens crystallization kinetics of iPP and leads to higher transparency of iPP films. Upon the incorporation of siloxane-silsesquioxane resin, no further effect on iPP crystallization kinetics is evidenced by calorimetry, optical microscopy, and X-ray diffraction analysis. Transparency of iPP-based composites is improved upon the addition of sorbitol, but decreased when SiOPh is added to the formulation. The composites are also stiffer, compared to neat polypropylene with a decreased elongation at break and increased Young's modulus values, with increasing amounts of fillers. The effect of the siloxane-silsesquioxane resin on properties of iPP/NX8000/SiOPh composites was explained taking into account compatibility of the components and morphology of the composites. © 2016 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 43476. [ABSTRACT FROM AUTHOR]