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Inserting CO2 into Aryl C−H Bonds of Metal-Organic Frameworks: CO2 Utilization for Direct Heterogeneous C−H Activation.
- Source :
- Angewandte Chemie; 4/25/2016, Vol. 128 Issue 18, p5562-5566, 5p
- Publication Year :
- 2016
-
Abstract
- Described for the first time is that carbon dioxide (CO<subscript>2</subscript>) can be successfully inserted into aryl C−H bonds of the backbone of a metal-organic framework (MOF) to generate free carboxylate groups, which serve as Brønsted acid sites for efficiently catalyzing the methanolysis of epoxides. The work delineates the very first example of utilizing CO<subscript>2</subscript> for heterogeneous C−H activation and carboxylation reactions on MOFs, and opens a new avenue for CO<subscript>2</subscript> chemical transformations under mild reaction conditions. [ABSTRACT FROM AUTHOR]
- Subjects :
- CARBON dioxide
CHEMICAL bonds
METAL-organic frameworks
METHANOLYSIS
EPOXY compounds
Subjects
Details
- Language :
- English
- ISSN :
- 00448249
- Volume :
- 128
- Issue :
- 18
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie
- Publication Type :
- Academic Journal
- Accession number :
- 114818492
- Full Text :
- https://doi.org/10.1002/ange.201511484