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Rational design of Nd3+-sensitized multifunctional nanoparticles with highly dominant red emission.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 5/28/2016, Vol. 45 Issue 20, p8440-8446, 7p
- Publication Year :
- 2016
-
Abstract
- Controlling excitation and emission wavelengths on demand is very significant in bioimaging. Up-conversion nanoparticles (UCNPs) emit visible light upon near-infrared (NIR) light excitation and are well studied in bioimaging. Red emission is usually preferred to green due to its higher tissue penetration depth in bioimaging. Herein, dominant red emission has been achieved under 808 nm excitation based on the designed α-NaYbF<subscript>4</subscript>:Mn<superscript>2+</superscript>/Er<superscript>3+</superscript>@NaLuF<subscript>4</subscript>:Mn<superscript>2+</superscript>/Yb<superscript>3+</superscript>@NaNdF<subscript>4</subscript>:Yb<superscript>3+</superscript>@NaGdF<subscript>4</subscript> (C@S1@S2@S3) nanostructure. The rationally designed interlayer shell NaLuF<subscript>4</subscript>:Mn<superscript>2+</superscript>/Yb<superscript>3+</superscript> could efficiently filter unwanted energy back-transfer from Er<superscript>3+</superscript> to Nd<superscript>3+</superscript> and the outmost shell NaGdF<subscript>4</subscript> could prevent excitation energy from surface-related quenching. The lifetime of <superscript>4</superscript>F<subscript>9/2</subscript>→<superscript>4</superscript>I<subscript>15/2</subscript> transition of Er<superscript>3+</superscript> could be as high as 0.7 ms. Moreover, C@S1@S2@S3 UCNPs also possess effective contrast efficiency for both X-ray computed tomography (CT) and magnetic resonance (MR) imaging. The designed multifunctional UCNPs could be used as a potential multimodal bioprobe in bioimaging applications. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 45
- Issue :
- 20
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 115407925
- Full Text :
- https://doi.org/10.1039/c6dt00707d