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Crystal Structure and Magnetic Properties of a Copper(II) Chloride Complex with Nitronyl Nitroxide.
- Source :
- Journal of Coordination Chemistry; 3/1/2002, Vol. 55 Issue 3, p293-299, 7p, 1 Diagram, 3 Charts, 1 Graph
- Publication Year :
- 2002
-
Abstract
- A new compound [Cu(NITPhCH 3 ) 2 Cl 2 ] (NITPhCH 3 2-(4-methyl-phenyl)-4,4,5,5-tetramethyl-imidazoline-1-oxyl-3-oxide) has been characterized spectroscopically. A crystal structure analysis has shown the copper ion to be planar, coordinated by two chlorine atoms and two oxygen (nitroxyl) atoms. Based on magnetic susceptibility measurements the compound was found to exhibit a moderately strong antiferromagnetic interaction (J=-107.44 cm -1 ) between copper(II) and the radical. [ABSTRACT FROM AUTHOR]
- Subjects :
- MAGNETIC properties
COPPER
COMPLEX compounds
NITROXIDES
TRANSITION metal ions
Subjects
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 55
- Issue :
- 3
- Database :
- Complementary Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 11548801
- Full Text :
- https://doi.org/10.1080/00958970211892