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Synthesis, Structure and Characterization of the Cyano-Bridged Heteropolymer Poly{[Bis(Trimethylenediamine)Copper(II)][Hexacyanocobalt(III)]} Perchlorate Dihydrate with a Two-Dimensional Framework.
- Source :
- Journal of Coordination Chemistry; 10/1/2002, Vol. 55 Issue 10, p1191-1198, 8p, 3 Diagrams, 3 Charts, 1 Graph
- Publication Year :
- 2002
-
Abstract
- The complex [Cu(tn) 2 ] 2 [Co(CN) 6 ](ClO 4 )ċ2H 2 O (tn = trimethylenediamine) has been prepared and characterized by elemental analysis, IR, electronic and electronic spin resonance spectra and magnetic properties. The x-ray structure analysis shows that each [Co(CN) 6 ] 3- ion coordinates to four [Cu(tn) 2 ] 2+ cations through four cyano nitrogen atoms in the same plane, providing a two-dimensional square network structure, formed from Co-CN-Cu(tn) 2 -NC-Co linkages. [ABSTRACT FROM AUTHOR]
- Subjects :
- POLYMERS
COPPER
TRANSITION metals
COMPLEX compounds
COORDINATION compounds
Subjects
Details
- Language :
- English
- ISSN :
- 00958972
- Volume :
- 55
- Issue :
- 10
- Database :
- Complementary Index
- Journal :
- Journal of Coordination Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 11548887
- Full Text :
- https://doi.org/10.1080/0095897021000025228