Semiconductive Nanotube Array Constructed from Giant [PbII18I54(I2)9] Wheel Clusters.

Crystalline nanotube array would create great opportunity for novel electrical application. Herein we report the first example of a metal halide based crystalline nanotube array which is constructed from an unprecedented giant [Pb^II₁₈I₅₄(I₂)₉] wheel cluster, as determined by synchrotron Xray diffraction. The electrical properties of the single crystal were studied and the present compound shows typical semiconductivity and highly anisotropic conductivity. [ABSTRACT FROM AUTHOR]