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Nanoscale Microstructure and Chemistry of Cu2ZnSnS4/CdS Interface in Kesterite Cu2ZnSnS4 Solar Cells.
- Source :
- Advanced Energy Materials; 8/10/2016, Vol. 6 Issue 15, pn/a-N.PAG, 10p
- Publication Year :
- 2016
-
Abstract
- Sulfurization with various atmosphere and postheat treatments has been reported for earth abundant kesterite Cu<subscript>2</subscript>ZnSnS<subscript>4</subscript> (CZTS) preparation as cost-effective material for next-generation solar cells. A full understanding of the nanoscale microstructure and chemistry of CZTS/CdS interface obtained from these different fabrication routes is currently lacking, yet is critical to developing optimal processing routes for high-performance kesterite solar cells. Here, the first detailed investigation of the interfacial microstructure and chemistry of CdS/Cu<subscript>2</subscript>ZnSnS<subscript>4</subscript> heterojunctions is presented. For CZTS obtained from sulfurization in a sulfur-only atmosphere where highly defective surfaces are present, air annealing followed by etching in the initial stage of chemical bath deposition (CBD) process can effectively eliminate interfacial defects and allow the epitaxial growth of CBD-CdS, improving the minority lifetime, open circuit voltage ( V<subscript>OC</subscript>), and fill factor (FF) of the devices, while blocking Cd diffusion and deteriorating short circuit current ( J<subscript>sc</subscript>). For CZTS from sulfurization in a combined sulfur and SnS atmosphere where CBD-CdS can directly epitaxially grow on CZTS and Cd-diffusion is clearly observed, associated devices show the longest lifetime and the highest efficiency of 8.76%. Epitaxial growth of CdS and Cd diffusion into CZTS are found to be two crucial features minimizing interfacial recombination and achieving high-efficiency devices. This will not only enhance the understanding of the device structure and physics of kesterite based solar cells, but also provide an effective way for designing other chalcogenide heterojunction solar cells. [ABSTRACT FROM AUTHOR]
- Subjects :
- NANOSTRUCTURED materials
MICROSTRUCTURE
KESTERITE
ZINC sulfide
SOLAR cells
Subjects
Details
- Language :
- English
- ISSN :
- 16146832
- Volume :
- 6
- Issue :
- 15
- Database :
- Complementary Index
- Journal :
- Advanced Energy Materials
- Publication Type :
- Academic Journal
- Accession number :
- 117320485
- Full Text :
- https://doi.org/10.1002/aenm.201600706