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Enhancement of magnetic anisotropy in a Mn–Bi heterobimetallic complex.
- Source :
- Chemical Communications; 10/1/2016, Vol. 52 Issue 76, p11394-11397, 4p
- Publication Year :
- 2016
-
Abstract
- A novel Mn<superscript>2+</superscript>…Bi<superscript>3+</superscript> heterobimetallic complex, featuring the closest Mn…Bi interaction for a paramagnetic molecular species, exhibits unusually large axial zero-field splitting. We attribute this enhancement to the proximity of Mn<superscript>2+</superscript> to a heavy main group element, namely, bismuth. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 52
- Issue :
- 76
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 118125436
- Full Text :
- https://doi.org/10.1039/c6cc06369a