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Iterative C−H Functionalization Leading to Multiple Amidations of Anilides.
- Source :
- Angewandte Chemie International Edition; 4/3/2017, Vol. 56 Issue 15, p4256-4260, 5p
- Publication Year :
- 2017
-
Abstract
- Polyaminobenzenes were synthesized by the ruthenium-catalyzed iterative C−H amidation of anilides using dioxazolones as an amino source. This strategy could be implemented by the sequential activation of C−H bonds of formerly generated compounds by cascade chelation assistance of newly installed amide groups. Computational studies provided a rationale. [ABSTRACT FROM AUTHOR]
- Subjects :
- CARBON-hydrogen bonds
AMIDATION
ANILIDES
ACTIVATION (Chemistry)
CHELATION
Subjects
Details
- Language :
- English
- ISSN :
- 14337851
- Volume :
- 56
- Issue :
- 15
- Database :
- Complementary Index
- Journal :
- Angewandte Chemie International Edition
- Publication Type :
- Academic Journal
- Accession number :
- 122099880
- Full Text :
- https://doi.org/10.1002/anie.201701138