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Synthesis and Adsorption Properties of Ca-Al Layered Double Hydroxides for the Removal of Aqueous Fluoride.
- Source :
- Water, Air & Soil Pollution; Jan2017, Vol. 228 Issue 1, p1-7, 7p
- Publication Year :
- 2017
-
Abstract
- Ca-Al layered double hydroxides (LDHs) with different Ca/Al molar ratios were composited at pH ranges, using a co-precipitation method, and were experimented to remove fluoride from wastewater and studied in terms of isotherm models such as Langmuir and Freundlich reactions. The composite LDHs were characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and Thermogravimetric analysis (TGA). The results showed that different synthesis conditions of Ca-Al LDHs had an influence on their morphology, layered structure, and particle size distribution, which substantially affected the uptake capacity for aqueous fluoride. LDHs with the Ca/Al molar ratio of 2 and synthesized at the pH of 12 had the highest capacity for the fluoride removal (e.g., 146.6 mg/g) and such reaction reached an equilibrium within 1 h. The Freundlich model was a better fit for this study. The high adsorption method of Ca-Al LDHs can be favorable to removing fluoride from wastewater streams. [ABSTRACT FROM AUTHOR]
Details
- Language :
- English
- ISSN :
- 00496979
- Volume :
- 228
- Issue :
- 1
- Database :
- Complementary Index
- Journal :
- Water, Air & Soil Pollution
- Publication Type :
- Academic Journal
- Accession number :
- 122850924
- Full Text :
- https://doi.org/10.1007/s11270-016-3160-0