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One-pot formation of hydrazide macrocycles with modified cavities: an example of pH-sensitive unimolecular cation channels.
- Source :
- Chemical Communications; 5/11/2017, Vol. 53 Issue 38, p5322-5325, 4p
- Publication Year :
- 2017
-
Abstract
- A series of pH-sensitive, cation-selective hydrazide macrocyclic channels have been synthesized. The macrocyclic channels bear multiple carboxyls in the inner cavity, which have a significant impact on their membrane-incorporation ability and NH<subscript>4</subscript><superscript>+</superscript> transport activity. Moreover, the K<superscript>+</superscript>/Cl<superscript>−</superscript> selectivities of the macrocyclic channels can be tuned by the pH value of the electrolyte. [ABSTRACT FROM AUTHOR]
- Subjects :
- HYDRAZIDES
MACROCYCLIC compounds
ELECTROLYTES
Subjects
Details
- Language :
- English
- ISSN :
- 13597345
- Volume :
- 53
- Issue :
- 38
- Database :
- Complementary Index
- Journal :
- Chemical Communications
- Publication Type :
- Academic Journal
- Accession number :
- 122932228
- Full Text :
- https://doi.org/10.1039/c7cc02076g