Back to Search
Start Over
Engaging dual donor sites within an N-heterocyclic olefin phosphine ligand.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 51/4/2017, Vol. 46 Issue 18, p5946-5954, 9p
- Publication Year :
- 2017
-
Abstract
- By investigating the coordination chemistry of a neutral N-heterocyclic olefin phosphine ligand, a new digold(i) chloride complex was discovered, demonstrating that mixed element (P/C) donor sites can be accessed at the same time. However attempts to extend this strategy for the preparation of heterobimetallic complexes featuring copper(i) and gold(i) centers with this mixed donor ligand were unsuccessful. The related monometallic copper(i) and gold(i) iodide complexes were discovered to be emissive in the solid state. [ABSTRACT FROM AUTHOR]
- Subjects :
- HETEROCYCLIC compounds
PHOSPHINES
LIGANDS (Chemistry)
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 46
- Issue :
- 18
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 122953483
- Full Text :
- https://doi.org/10.1039/c7dt00398f