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Engaging dual donor sites within an N-heterocyclic olefin phosphine ligand.

Authors :
Lui, Melanie W.
Shynkaruk, Olena
Oakley, Meagan S.
Sinelnikov, Regina
McDonald, Robert
Ferguson, Michael J.
Meldrum, Al
Klobukowski, Mariusz
Rivard, Eric
Source :
Dalton Transactions: An International Journal of Inorganic Chemistry; 51/4/2017, Vol. 46 Issue 18, p5946-5954, 9p
Publication Year :
2017

Abstract

By investigating the coordination chemistry of a neutral N-heterocyclic olefin phosphine ligand, a new digold(i) chloride complex was discovered, demonstrating that mixed element (P/C) donor sites can be accessed at the same time. However attempts to extend this strategy for the preparation of heterobimetallic complexes featuring copper(i) and gold(i) centers with this mixed donor ligand were unsuccessful. The related monometallic copper(i) and gold(i) iodide complexes were discovered to be emissive in the solid state. [ABSTRACT FROM AUTHOR]

Details

Language :
English
ISSN :
14779226
Volume :
46
Issue :
18
Database :
Complementary Index
Journal :
Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :
Academic Journal
Accession number :
122953483
Full Text :
https://doi.org/10.1039/c7dt00398f