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AgI-Promoted Difluoromethylation of Isocyanides To Give Difluoromethylated Phenanthridines.
- Source :
- European Journal of Organic Chemistry; 6/16/2017, Vol. 2017 Issue 22, p3145-3151, 7p
- Publication Year :
- 2017
-
Abstract
- An Ag<superscript>I</superscript>-mediated ethoxycarbonyldifluoromethylation of isocyanides has been developed. This radical cascade reaction involves the addition of difluoromethylene radical to the isocyanide functionality, and subsequent homolytic aromatic substitution to give difluoromethylated phenanthridines with a good functional-group tolerance. [ABSTRACT FROM AUTHOR]
- Subjects :
- ISOCYANIDES
METHYLATION
PHENANTHRIDINE
TOLERATION
FREE radical reactions
Subjects
Details
- Language :
- English
- ISSN :
- 1434193X
- Volume :
- 2017
- Issue :
- 22
- Database :
- Complementary Index
- Journal :
- European Journal of Organic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 123599201
- Full Text :
- https://doi.org/10.1002/ejoc.201700470