Covalent self-assembly of the specific RSSR isomer of 14-membered tetrakisphosphine.

Authors :: Wittmann, T. I.
Musina, E. I.
Krivolapov, D. B.
Litvinov, I. A.
Kondrashova, S. A.
Latypov, Sh. K.
Karasik, A. A.
Sinyashin, O. G.
Source :: Dalton Transactions: An International Journal of Inorganic Chemistry; 10/7/2017, Vol. 46 Issue 37, p12417-12420, 4p
Publication Year :: 2017
Abstract: The first representative of the specific RSSR isomer of 14-membered tetrakisphosphine has been obtained instead of the RRRR/SSSS isomer predicted according to the empirical rule formulated recently. The geometry of the obtained 14-P<subscript>4</subscript>N<subscript>2</subscript> is preorganized for the dicopper complex formation with the unique coordination mode in the row of P<subscript>4</subscript>N<subscript>2</subscript> corands. [ABSTRACT FROM AUTHOR]

Language :: English
ISSN :: 14779226
Volume :: 46
Issue :: 37
Database :: Complementary Index
Journal :: Dalton Transactions: An International Journal of Inorganic Chemistry
Publication Type :: Academic Journal
Accession number :: 125341573
Full Text :: https://doi.org/10.1039/c7dt03010j

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