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Li6Na3Sr14Al11P22O90: an oxo-centered Al3 cluster based phosphate constructed from two types of (3,6)-connected kgd layers.
- Source :
- Dalton Transactions: An International Journal of Inorganic Chemistry; 1/14/2018, Vol. 47 Issue 2, p298-301, 4p
- Publication Year :
- 2018
-
Abstract
- A novel and thermally stable aluminum phosphate Li<subscript>6</subscript>Na<subscript>3</subscript>Sr<subscript>14</subscript>Al<subscript>11</subscript>P<subscript>22</subscript>O<subscript>90</subscript> (1) has been achieved by using a solid-state molten method, which contains an oxo-centered trinuclear cluster and an anti-Lowenstein's rule Al–O–Al linkage and is constructed from two types of (3,6)-connected kgd layers [Al(Al<subscript>3</subscript>O)(PO<subscript>4</subscript>)<subscript>7</subscript>]<superscript>25−</superscript> and [Al(PO<subscript>4</subscript>)<subscript>2</subscript>]<superscript>3−</superscript>. The good optical transparency in the whole UV range and excellent thermal stability make the title compound a potential optical window material. [ABSTRACT FROM AUTHOR]
- Subjects :
- ALUMINUM phosphate
SOLID state chemistry
CHEMICAL stability
Subjects
Details
- Language :
- English
- ISSN :
- 14779226
- Volume :
- 47
- Issue :
- 2
- Database :
- Complementary Index
- Journal :
- Dalton Transactions: An International Journal of Inorganic Chemistry
- Publication Type :
- Academic Journal
- Accession number :
- 127072238
- Full Text :
- https://doi.org/10.1039/c7dt03854b