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Synthesis of 6-Thiocyanatophenanthridines by Visible-Light- and Air-Promoted Radical Thiocyanation of 2-Isocyanobiphenyls.
- Source :
- Synlett; 2018, Vol. 29 Issue 2, p176-180, 5p
- Publication Year :
- 2018
-
Abstract
- A convenient, efficient, and metal-free synthesis of 6-thiocyanatophenanthridines by visible-light- and air-mediated, eosin Y-catalyzed, sequential radical cyclization and aromatization of 2-isocyanobiphenyls with ammonium thiocyanate is reported. Advantageously, the protocol utilizes inexpensive, clean, and sustainable natural resources such as visible light and atmospheric oxygen at room temperature in a one-pot procedure. [ABSTRACT FROM AUTHOR]
- Subjects :
- PHENYL compounds
VISIBLE spectra
CHEMICAL synthesis
Subjects
Details
- Language :
- English
- ISSN :
- 09365214
- Volume :
- 29
- Issue :
- 2
- Database :
- Complementary Index
- Journal :
- Synlett
- Publication Type :
- Academic Journal
- Accession number :
- 127318621
- Full Text :
- https://doi.org/10.1055/s-0036-1590921